- CasNo 2277-19-2
- Purity 99%
CIS-6-NONENAL Good Manufacturer supply High Quality 2277-19-2
- Molecular Formula: C9H16 O
- Molecular Weight: 140.225
- Appearance/Colour: clear colorless to pale yellow liquid
- Vapor Pressure: 0.449mmHg at 25°C
- Melting Point: -28°C (estimate)
- Refractive Index: n20/D 1.442(lit.)
- Boiling Point: 194.1°Cat760mmHg
- Flash Point: 65.1°C
- PSA： 17.07000
- Density: 0.834g/cm3
- LogP: 2.71190
CIS-6-NONENAL(Cas 2277-19-2) Usage
|
Preparation |
By catalytic hydrogenation of 6-nonynal diethyl acetal followed by hydrolysis |
|
Safety Profile |
Low toxicity by ingestion and skin contact. A skin irritant. Flammable liquid when exposed to heat, sparks, or flame. When heated to decomposition it emits acrid smoke and irritating fumes. |
|
Aroma threshold values |
Detection: 0.005 ppb |
|
Taste threshold values |
Taste characteristics at 25 ppm: green cucumber and melon with a waxy vegetative nuance |
InChI:InChI=1/C9H16O/c1-2-3-4-5-6-7-8-9-10/h3-4,9H,2,5-8H2,1H3/b4-3-
2277-19-2 Relevant articles
A Simple, Mild and General Oxidation of Alcohols to Aldehydes or Ketones by SO2F2/K2CO3 Using DMSO as Solvent and Oxidant
Zha, Gao-Feng,Fang, Wan-Yin,Leng, Jing,Qin, Hua-Li
supporting information, p. 2262 - 2267 (2019/04/17)
A practical, general and mild oxidation ...
A Transition-Metal-Free One-Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2
Jiang, Ying,Sun, Bing,Fang, Wan-Yin,Qin, Hua-Li
supporting information, p. 3190 - 3194 (2019/05/21)
A new transition-metal-free one-pot casc...
NiH-Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3)?H Alkylation of Alkenes
Zhou, Fang,Zhu, Jin,Zhang, Yao,Zhu, Shaolin
supporting information, p. 4058 - 4062 (2018/03/21)
The terminal-selective, remote C(sp3)?H ...
Design, synthesis, and biological evaluation of N-Alkylated deoxynojirimycin (DNJ) derivatives for the treatment of dengue virus infection
Yu, Wenquan,Gill, Tina,Wang, Lijuan,Du, Yanming,Ye, Hong,Qu, Xiaowang,Guo, Ju-Tao,Cuconati, Andrea,Zhao, Kang,Block, Timothy M.,Xu, Xiaodong,Chang, Jinhong
supporting information; experimental part, p. 6061 - 6075 (2012/08/14)
We recently described the discovery of o...
2277-19-2 Process route
-
-
31502-19-9,40709-05-5,35854-86-5
(Z)-6-nonenol
-
-
2277-19-2
cis-6-nonenal
Conditions
| Conditions | Yield |
|---|---|
|
(Z)-6-nonenol;
With
oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane;
at -78 ℃;
for 0.25h;
Inert atmosphere;
With
triethylamine;
In
dichloromethane;
at -78 - -40 ℃;
for 2h;
Inert atmosphere;
|
93%
|
|
With
silica gel; pyridinium chlorochromate;
In
dichloromethane;
at 20 ℃;
for 4h;
Inert atmosphere;
|
89%
|
|
With
fluorosulfonyl fluoride; potassium carbonate; dimethyl sulfoxide;
at 20 ℃;
for 12h;
chemoselective reaction;
|
87%
|
|
With
Dess-Martin periodane;
In
dichloromethane;
at 20 ℃;
for 2h;
|
60%
|
|
With
fluorosulfonyl fluoride; potassium carbonate; dimethyl sulfoxide;
at 20 ℃;
|
-
-
80634-88-4
(Z)-2-(oct-5-en-1-yl)-1,3-dioxolane
-
-
2277-19-2
cis-6-nonenal
Conditions
| Conditions | Yield |
|---|---|
|
With
sulfuric acid;
for 10h;
Ambient temperature;
|
90%
|
2277-19-2 Upstream products
-
80634-88-4
(Z)-2-(oct-5-en-1-yl)-1,3-dioxolane
-
1136196-28-5
C15 H32 OSi
-
629-11-8
1,6-hexanediol
-
31502-19-9
(Z)-6-nonenol
2277-19-2 Downstream products
-
81980-06-5
Z-7-decen-2-ol
-
76123-38-1
cis-2-E-propenylcyclohexanol
-
139606-58-9
(Z)-1-phenylnon-6-en-1-ol
-
81980-06-5
7-decen-2-ol
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